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Aluminium arsenate : ウィキペディア英語版
Aluminium arsenate

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Aluminium arsenate is a inorganic compound with the formula AlAsO4.〔(Aluminum arsenate at Chemister )〕 It is most commonly found as an octahydrate. It is a colourless solid that is produced by the reaction between sodium arsenate and a soluble aluminium salt. Aluminium arsenate occurs naturally as the mineral mansfieldite.〔Chemistry of Arsenic, Antimony, and Bismuth, Edited by N. C. Norman. page 131,〕 A synthetic hydrate of aluminium arsenate is produced by hydrothermal method. with the formulation, Al2O3.3As2O5.10H2O.〔http://www.minsocam.org/ammin/AM39/AM39_1005.pdf〕
Modification of aluminium orthoarsenate was carried out by heating different samples to different temperatures.Both amorphous and crystalline forms were obtained.〔B. Sharan "A new modification of aluminum ortho-arsenate" Acta Cryst. 1959, vol. 12, 948-949. 〕 The solubility product was determined to be 10−18.06. for Aluminium arsenate of formula AlAsO4.3.5H2O〔Fernando L. Pantuzzo, Luciano R.G. Santos, Virginia S.T. Ciminelli "Solubility-product constant of an amorphous aluminum-arsenate phase (AlAsO4·3.5H2O) AT 25 °C" Hydrometallurgy
Volumes 2014, 144–145, Pages 63–68. 〕
Like gallium arsenate and boron arsenate, it adopts the α-quartz-type structure. The high pressure form has a rutile-type structure in which aluminium and arsenic are six-coordinate.
==References==


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